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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Recent Uses of Iron (III) Chloride in Organic Synthesis

Author(s): David D. Diaz, Pedro O. Miranda, Juan I. Padron and ">Víctor S. Martin

Volume 10, Issue 4, 2006

Page: [457 - 476] Pages: 20

DOI: 10.2174/138527206776055330

Price: $65

Abstract

Iron (III) chloride is extensively used in organic synthesis as an ideal Lewis acid since it is an inexpensive, efficient, stable, environmentally friendly and a convenient agent for several useful reactions such as; polymerisations, oxidations, oxidative couplings, reductions, C C bond formation, Ferrier rearrangement, one-pot multicomponent condensations, Friedel-Crafts reactions, cyclisations, glycosidation, Prins-type cyclisation, deprotection of various functional groups, and as a reagent in key steps of natural products synthesis. This comprehensive review attempts to cover the advances in this field, which have occurred in the last five years.

Keywords: Polymerisation reactions, chromophores, Deprotections, Oxidative Couplings, 3,3-diaryl alkylpropionates, Carbometalation, alkynes


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