Abstract
This work presents the main methods of synthesis for [4.n]cyclophanes and reveals the possibilities to use common methods or peculiar ones in order to obtain more efficient access to different cyclophanes which exhibit a four membered bridge. The conformational behavior of [4.n]cyclophanes involving the flexibility of the bridges and the rotational behavior of the aromatic rings is discussed in correlation with the length of the bridges and with the nature of the aromatic rings. The complexation ability of the named cyclophanes, their reactivity and applications are also discussed.
Keywords: cyclophanes, synthesis, aromatic rings, cyclophenylenealkane, Heterophanes, Aliphanes
Current Organic Chemistry
Title: [4.n]Cyclophanes
Volume: 13 Issue: 5
Author(s): Niculina Daniela Bogdan and Ion Grosu
Affiliation:
Keywords: cyclophanes, synthesis, aromatic rings, cyclophenylenealkane, Heterophanes, Aliphanes
Abstract: This work presents the main methods of synthesis for [4.n]cyclophanes and reveals the possibilities to use common methods or peculiar ones in order to obtain more efficient access to different cyclophanes which exhibit a four membered bridge. The conformational behavior of [4.n]cyclophanes involving the flexibility of the bridges and the rotational behavior of the aromatic rings is discussed in correlation with the length of the bridges and with the nature of the aromatic rings. The complexation ability of the named cyclophanes, their reactivity and applications are also discussed.
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Cite this article as:
Bogdan Daniela Niculina and Grosu Ion, [4.n]Cyclophanes, Current Organic Chemistry 2009; 13 (5) . https://dx.doi.org/10.2174/138527209787582231
DOI https://dx.doi.org/10.2174/138527209787582231 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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