Abstract
This paper focuses on the latest developments in asymmetric epoxidation of electron-deficient olefins since the review by Porter and Skidmore on chiral ligand-metal peroxide systems, polyamino acid catalysed and organocatalysed epoxidations. Particular attention has been paid to the most recent advances using chiral pyrrolidines as organocatalysts.
Keywords: Asymmetric epoxidation, electron deficient olefins, organocatalysis, dioxiranes, chiral ligand, –, metal peroxide systems, Juliá Colonna epoxidation
Current Organic Synthesis
Title: Asymmetric Epoxidation of Electron-Deficient Olefins
Volume: 5 Issue: 3
Author(s): David Diez, Marta G. Nunez, Ana B. Anton, P. Garcia, R. .F. Moro, N. M. Garrido, Isidro S. Marcos, P. Basabe and Julio G. Urones
Affiliation:
Keywords: Asymmetric epoxidation, electron deficient olefins, organocatalysis, dioxiranes, chiral ligand, –, metal peroxide systems, Juliá Colonna epoxidation
Abstract: This paper focuses on the latest developments in asymmetric epoxidation of electron-deficient olefins since the review by Porter and Skidmore on chiral ligand-metal peroxide systems, polyamino acid catalysed and organocatalysed epoxidations. Particular attention has been paid to the most recent advances using chiral pyrrolidines as organocatalysts.
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Cite this article as:
Diez David, Nunez G. Marta, Anton B. Ana, Garcia P., Moro .F. R., Garrido M. N., Marcos S. Isidro, Basabe P. and Urones G. Julio, Asymmetric Epoxidation of Electron-Deficient Olefins, Current Organic Synthesis 2008; 5 (3) . https://dx.doi.org/10.2174/157017908785133429
DOI https://dx.doi.org/10.2174/157017908785133429 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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Exploring the Role of Chemical Graph Theory in Advancing Current Organic Synthesis
Organic synthesis is a fundamental discipline in chemistry, crucial for the creation of complex molecules with diverse applications in pharmaceuticals, materials science, and beyond. However, the process of designing efficient synthetic routes for target molecules remains challenging. Chemical graph theory, a branch of theoretical chemistry, offers powerful tools for understanding ...read more
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