Abstract
Lewis and Bronsted base catalysis are rapidly growing areas in organocatalysis. Numerous binaphthyl-derived chiral base catalysts has been developed over the last years. Recent progress in the chiral Lewis and Bronsted base catalysis has been reviewed with a focus being placed on mono-functional catalysts, including primary and secondary diamines, guanidines, phosphines and phosphineoxides; bi- and multifunctional catalysts, covering secondary and/or tertiary amine and phosphine derivatives assisted with urea/thiourea hydrogen bond donors or Lewis/ Bronsted acids.
Keywords: Asymmetric organocatalysis, bi-/multi-functional catalysis, binaphthyl-derived organocatalysts, Bronsted bases, Lewis bases, urea/thioureas, Primary Diamines, Guanidine Derivatives, Secondary Diamines, Chiral Phosphineoxides, Alcohol-Assisted Tertiary Amines, B- OR LI-BINOL COMPLEXES, phase transfer catalysts (PTC), tetramethylguanidine (TMG), chemoselective
Current Organic Chemistry
Title: Binaphthyl-Derived Mono-, Bi- and Multi-Functional Lewis and Brønsted Base Organocatalysts: A New Vista for Asymmetric Synthesis
Volume: 15 Issue: 13
Author(s): Matthias Freund, Sebastian Schenker, Alexandru Zamfir and Svetlana B. Tsogoeva
Affiliation:
Keywords: Asymmetric organocatalysis, bi-/multi-functional catalysis, binaphthyl-derived organocatalysts, Bronsted bases, Lewis bases, urea/thioureas, Primary Diamines, Guanidine Derivatives, Secondary Diamines, Chiral Phosphineoxides, Alcohol-Assisted Tertiary Amines, B- OR LI-BINOL COMPLEXES, phase transfer catalysts (PTC), tetramethylguanidine (TMG), chemoselective
Abstract: Lewis and Bronsted base catalysis are rapidly growing areas in organocatalysis. Numerous binaphthyl-derived chiral base catalysts has been developed over the last years. Recent progress in the chiral Lewis and Bronsted base catalysis has been reviewed with a focus being placed on mono-functional catalysts, including primary and secondary diamines, guanidines, phosphines and phosphineoxides; bi- and multifunctional catalysts, covering secondary and/or tertiary amine and phosphine derivatives assisted with urea/thiourea hydrogen bond donors or Lewis/ Bronsted acids.
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Cite this article as:
Freund Matthias, Schenker Sebastian, Zamfir Alexandru and B. Tsogoeva Svetlana, Binaphthyl-Derived Mono-, Bi- and Multi-Functional Lewis and Brønsted Base Organocatalysts: A New Vista for Asymmetric Synthesis, Current Organic Chemistry 2011; 15 (13) . https://dx.doi.org/10.2174/138527211796150750
DOI https://dx.doi.org/10.2174/138527211796150750 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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