Frontiers in Natural Product Chemistry

Volume: 1

Stereocontrol in Organic Synthesis Using Silicon Compounds

Author(s): Ian Fleming

Pp: 55-64 (10)

DOI: 10.2174/978160805212710501010055

* (Excluding Mailing and Handling)

Abstract

Electronic control of diastereoselectivity is discussed; only electrophilic attack adjacent to a stereogenic centre carrying an electropositive element 3 makes a coherent story.

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