Abstract
Nano-poly(3-methoxythiophene) (NPMOT) was electrochemically synthesized on an ITO surface in the ionic liquid 1-butyl-3- methyl-imidazolium tetrafluoroborate ([BMIM]BF4) by a potentiodynamic polymerization method. NPMOT was characterized by fourier- transform infrared spectroscopies (FTIR) and scanning electron microscopy (SEM). Spectroelectrochemistry and electrochromic properties of the NPMOT films were characterized using various experiment techniques in [BMIM]BF4. The thin films were red at its neutral state. After oxidization of the NPMOT films, the films underwent reversible change to the blue. Via kinetic studies, switching time and the maximum optical contrast % ∆T were found to be 2.4 s and 33.1% for NPMOT films.
Keywords: Poly (3-methoxythiophene), ionic liquid, electrochromism, electropolymerization, Electrochemical Synthesis, kinetic studies, optical contrast
Current Nanoscience
Title:Electrochemical Synthesis and Electrochromic Properties of Nano-poly(3-methoxythiophene) in a Room Temperature Ionic Liquid
Volume: 8 Issue: 3
Author(s): Xu Chun Song, Xia Wang, Yi Fan Zheng and Hao Yong Yin
Affiliation:
Keywords: Poly (3-methoxythiophene), ionic liquid, electrochromism, electropolymerization, Electrochemical Synthesis, kinetic studies, optical contrast
Abstract: Nano-poly(3-methoxythiophene) (NPMOT) was electrochemically synthesized on an ITO surface in the ionic liquid 1-butyl-3- methyl-imidazolium tetrafluoroborate ([BMIM]BF4) by a potentiodynamic polymerization method. NPMOT was characterized by fourier- transform infrared spectroscopies (FTIR) and scanning electron microscopy (SEM). Spectroelectrochemistry and electrochromic properties of the NPMOT films were characterized using various experiment techniques in [BMIM]BF4. The thin films were red at its neutral state. After oxidization of the NPMOT films, the films underwent reversible change to the blue. Via kinetic studies, switching time and the maximum optical contrast % ∆T were found to be 2.4 s and 33.1% for NPMOT films.
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Cite this article as:
Chun Song Xu, Wang Xia, Fan Zheng Yi and Yong Yin Hao, Electrochemical Synthesis and Electrochromic Properties of Nano-poly(3-methoxythiophene) in a Room Temperature Ionic Liquid, Current Nanoscience 2012; 8 (3) . https://dx.doi.org/10.2174/157341312800620322
DOI https://dx.doi.org/10.2174/157341312800620322 |
Print ISSN 1573-4137 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6786 |
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