Abstract
Ketones were prepared by a modified Nef reaction using heterocyclic aryl nitroalkenes to react in a Fe-FeCl3-CH3COOH mixture with higher yield over 50% in sharp contrast with in Fe-HCl mixture with lower yield less than 30%, thus it’s cost-saving and relative environment friendly.
Keywords: Heterocyclic aryl nitroalkenes, Fe-FeCl3-CH3COOH system, ketones, Nef reaction, reductive hydrolysis.
Current Organic Synthesis
Title:Higher Efficiently Conversion of Heterocyclic Aryl Nitroalkenes to Ketones
Volume: 11 Issue: 6
Author(s): Dushu Huang, Jin-Gang Yu, Wei Liu, Yunhui Long and Jing Wang
Affiliation:
Keywords: Heterocyclic aryl nitroalkenes, Fe-FeCl3-CH3COOH system, ketones, Nef reaction, reductive hydrolysis.
Abstract: Ketones were prepared by a modified Nef reaction using heterocyclic aryl nitroalkenes to react in a Fe-FeCl3-CH3COOH mixture with higher yield over 50% in sharp contrast with in Fe-HCl mixture with lower yield less than 30%, thus it’s cost-saving and relative environment friendly.
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Cite this article as:
Huang Dushu, Yu Jin-Gang, Liu Wei, Long Yunhui and Wang Jing, Higher Efficiently Conversion of Heterocyclic Aryl Nitroalkenes to Ketones, Current Organic Synthesis 2014; 11 (6) . https://dx.doi.org/10.2174/1570179411666140424232227
DOI https://dx.doi.org/10.2174/1570179411666140424232227 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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