Abstract
The Suzuki cross-coupling reaction, which is commonly referred to simply as the “Suzuki reaction” and uses palladium as a catalyst, has become an efficient tool for constructing C–C bonds over the past two decades. This paper reviews recent advances in the use of this reaction with heterogeneous palladium catalysts. The heterogenization of homogeneous catalysts by incorporation into an inorganic support (silica, mainly) or an organic polymer is currently of one the hottest research topics. Although heterogeneous catalysts based on uncomplexed Pd(II) or Pd(0) deposited on an inorganic supports such as carbon, silica or a zeolite remain in wide use, new catalysts consisting of Pd(0) nanoparticles entrapped in or deposited onto an organic or inorganic support are being increasingly used in the Suzuki reaction.
Keywords: Suzuki reaction, Cross-coupling reaction, Pd heterogenous catalysts
Current Organic Chemistry
Title:Recent Advances in the Heterogeneous Palladium-Catalysed Suzuki Cross-Coupling Reaction
Volume: 16 Issue: 9
Author(s): Manuel Mora, César Jiménez-Sanchidrián and José Rafael Ruiz
Affiliation:
Keywords: Suzuki reaction, Cross-coupling reaction, Pd heterogenous catalysts
Abstract: The Suzuki cross-coupling reaction, which is commonly referred to simply as the “Suzuki reaction” and uses palladium as a catalyst, has become an efficient tool for constructing C–C bonds over the past two decades. This paper reviews recent advances in the use of this reaction with heterogeneous palladium catalysts. The heterogenization of homogeneous catalysts by incorporation into an inorganic support (silica, mainly) or an organic polymer is currently of one the hottest research topics. Although heterogeneous catalysts based on uncomplexed Pd(II) or Pd(0) deposited on an inorganic supports such as carbon, silica or a zeolite remain in wide use, new catalysts consisting of Pd(0) nanoparticles entrapped in or deposited onto an organic or inorganic support are being increasingly used in the Suzuki reaction.
Export Options
About this article
Cite this article as:
Mora Manuel, Jiménez-Sanchidrián César and Rafael Ruiz José, Recent Advances in the Heterogeneous Palladium-Catalysed Suzuki Cross-Coupling Reaction, Current Organic Chemistry 2012; 16 (9) . https://dx.doi.org/10.2174/138527212800564358
DOI https://dx.doi.org/10.2174/138527212800564358 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
Calculation design of covalent/metal organic framework based catalysts
This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
Related Journals
- Author Guidelines
- Graphical Abstracts
- Fabricating and Stating False Information
- Research Misconduct
- Post Publication Discussions and Corrections
- Publishing Ethics and Rectitude
- Increase Visibility of Your Article
- Archiving Policies
- Peer Review Workflow
- Order Your Article Before Print
- Promote Your Article
- Manuscript Transfer Facility
- Editorial Policies
- Allegations from Whistleblowers
- Announcements
Related Articles
-
Current Non-viral Gene Therapy Strategies for the Treatment of Glioblastoma
Current Medicinal Chemistry Reduction of Genotoxicity of Carbamazepine to Human Lymphocytes by Pre-treatment with Vitamin B12
Current Molecular Pharmacology Prediction Oriented QSAR Modelling of EGFR Inhibition
Current Medicinal Chemistry Antibacterial Activity of Thioetherhydroxyethylsulfonamide Derivatives
Medicinal Chemistry Preliminary Anti-Coxsackie Activity of Novel 1-[4-(5,6-dimethyl(H)- 1H(2H)-benzotriazol-1(2)-yl)phenyl]-3-alkyl(aryl)ureas
Medicinal Chemistry Bioavailability of Endomorphins and the Blood-brain Barrier- A Review
Medicinal Chemistry Drug Discovery Today
Current Topics in Medicinal Chemistry Discussion on the Structural Modification and Anti-tumor Activity of Flavonoids
Current Topics in Medicinal Chemistry Pharmacological Management of Acutely Agitated Schizophrenic Patients
Current Pharmaceutical Design Pesticides as Estrogen Disruptors: QSAR for Selective ERα and ERβ Binding of Pesticides
Combinatorial Chemistry & High Throughput Screening The Impact of SSRI Use on the Clinical Outcome and Prognosis of COVID-19 Patients: A Single-Center Prospective Study
Current Psychopharmacology Clinical Presentation, Outcome and Risk Factors of Late-Onset Non- Infectious Pulmonary Complications After Allogeneic Stem Cell Transplantation
Current Stem Cell Research & Therapy Synthesis and Biological Evaluation of some Amide Derivatives Bearing Benzothiazole and Piperidine Moieties as Antimicrobial Agents
Letters in Drug Design & Discovery Therapeutic Potential of Nitrate Esters of Commonly Used Drugs
Current Topics in Medicinal Chemistry Pharmacological Activities and Therapeutic Potential of Kaempferitrin in Medicine for the Treatment of Human Disorders: A Review of Medicinal Importance and Health Benefits
Cardiovascular & Hematological Disorders-Drug Targets Molecular Elucidation and Therapeutic Targeting for Combating COVID-19: Current Scenario and Future Prospective
Current Molecular Medicine Trait Anger, Hostility, and the Risk of Type 2 Diabetes and Diabetes- Related Complications: A Systematic Review of Longitudinal Studies
Current Diabetes Reviews The Antidiabetic PPARγ Ligands: An Update on Compounds in Development
Current Medicinal Chemistry - Immunology, Endocrine & Metabolic Agents Pathophysiology of Thrombosis and Potential Targeted Therapies in Antiphospholipid Syndrome
Current Vascular Pharmacology Dental Care during the COVID-19 Pandemic
Coronaviruses