Abstract
Phenothiazinyl primary amines were synthesized in moderate to excellent yields from cyano (oligo)phenothiazines by reduction with LiAlH4 in diethyl ether or with nBuNBH4 in dichloromethane. All representatives show first reversible oxidation waves, they are UV absorbing and dimers emit blue-green light upon UV excitation with substantial quantum yield.
Keywords: Amines, cyclic voltammetry, fluorescence, heterocycles, reduction, pharmaceuticals, hydrides, propylperazine, redox
Letters in Organic Chemistry
Title: Synthesis and Electronic Properties of Phenothiazinyl Primary Amines
Volume: 9 Issue: 3
Author(s): Larisa N. Mataranga-Popa, Adam W. Franz, Sarah Bay and Thomas J.J. Muller
Affiliation:
Keywords: Amines, cyclic voltammetry, fluorescence, heterocycles, reduction, pharmaceuticals, hydrides, propylperazine, redox
Abstract: Phenothiazinyl primary amines were synthesized in moderate to excellent yields from cyano (oligo)phenothiazines by reduction with LiAlH4 in diethyl ether or with nBuNBH4 in dichloromethane. All representatives show first reversible oxidation waves, they are UV absorbing and dimers emit blue-green light upon UV excitation with substantial quantum yield.
Export Options
About this article
Cite this article as:
N. Mataranga-Popa Larisa, W. Franz Adam, Bay Sarah and J.J. Muller Thomas, Synthesis and Electronic Properties of Phenothiazinyl Primary Amines, Letters in Organic Chemistry 2012; 9 (3) . https://dx.doi.org/10.2174/157017812800167529
DOI https://dx.doi.org/10.2174/157017812800167529 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
- Author Guidelines
- Graphical Abstracts
- Fabricating and Stating False Information
- Research Misconduct
- Post Publication Discussions and Corrections
- Publishing Ethics and Rectitude
- Increase Visibility of Your Article
- Archiving Policies
- Peer Review Workflow
- Order Your Article Before Print
- Promote Your Article
- Manuscript Transfer Facility
- Editorial Policies
- Allegations from Whistleblowers
Related Articles
-
Green Tea Catechins and Cardiovascular Health: An Update
Current Medicinal Chemistry The Impact of the Emerging Genomics Data on the Management of Agerelated Phenotypes in the Context of Cellular Senescence
Current Drug Targets Management of Vasculopathy in Connective Tissue Disease
Current Rheumatology Reviews The Effects of Vitamin C on Adriamycin-Induced Hypercholesterolemia in Rat
Current Nutrition & Food Science Genomic and Non-genomic Effects of Aldosterone
Current Signal Transduction Therapy Antiangiogenic Agents: Studies on Fumagillin and Curcumin Analogs
Current Pharmaceutical Design Editorial (Hot Topic: Cardiovascular Disease Biomarkers: from Tradition to Modernity)
Current Topics in Medicinal Chemistry Investigation on Risk Factor of Vascular Thrombotic Diseases in Patients with Obstructive Sleep Apnea Hypopnea Syndrome
Vascular Disease Prevention (Discontinued) Nitric Oxide Synthases and Their Natural Inhibitors
Current Enzyme Inhibition Clinical Utility of Neoadjuvant Endocrine Therapy for Hormone Receptor Positive Breast Cancer
Reviews on Recent Clinical Trials Management of the Low Cardiac Output Syndrome Following Surgery for Congenital Heart Disease
Current Cardiology Reviews Androgen Deficiency in Aging Male Questionnaire for the Clinical Detection of Testosterone Deficiency in a Population of Black Sub-Saharan African Men with Type 2 Diabetes Mellitus: Is it a Reliable Tool?
Current Diabetes Reviews Epigenetics in Ocular Diseases
Current Genomics Recent Advances in the Synthesis and Anticancer Activity of Some Molecules Other Than Nitrogen Containing Heterocyclic Moeities
Mini-Reviews in Medicinal Chemistry Impact of Delayed Whole Blood Processing Time on Plasma Levels of miR- 1 and miR-423-5p up to 24 Hours
MicroRNA Regulation of Insulin Synthesis and Secretion and Pancreatic Beta-Cell Dysfunction in Diabetes
Current Diabetes Reviews Biologic Therapy in Psoriasis: Safety Profile
Current Drug Safety Optimizing the Management of Uncontrolled Hypertension: What do Triple Fixed-Dose Drug Combinations Add?
Current Vascular Pharmacology Biological Active Ingredients of Traditional Chinese Herb Astragalus membranaceus on Treatment of Diabetes: A Systematic Review
Mini-Reviews in Medicinal Chemistry Antisynthetase Syndrome: A Review of Etiopathogenesis, Diagnosis and Management
Current Medicinal Chemistry