Abstract
During the past few years, Lewis-acidic ionic liquids (ILs) have emerged from their role as mere reaction media toward a role as novel catalytic systems. Iron-containing chloroferrate ionic liquids in particular offer a novel approach to sustainable and environmentally benign catalysis and can be applied in a surprising diversity of transformations. In this review, we present this emerging topic and report the application of chloroferrate ILs as solvents, catalysts or catalytic systems for a variety of chemical processes, with a particular focus on reactions leading to pharmaceutically active compounds or intermediates.
Keywords: Catalysis, Chloroferrate, Ionic liquids, Synthesis, Sustainable Catalysis, Solvent, 1.1. Friedel, –, Crafts Acylation
Current Organic Synthesis
Title: From Solvent to Sustainable Catalysis - Chloroferrate Ionic Liquids in Synthesis
Volume: 8 Issue: 6
Author(s): Katharina Bica, Sonja Leder and Peter Gaertner
Affiliation:
Keywords: Catalysis, Chloroferrate, Ionic liquids, Synthesis, Sustainable Catalysis, Solvent, 1.1. Friedel, –, Crafts Acylation
Abstract: During the past few years, Lewis-acidic ionic liquids (ILs) have emerged from their role as mere reaction media toward a role as novel catalytic systems. Iron-containing chloroferrate ionic liquids in particular offer a novel approach to sustainable and environmentally benign catalysis and can be applied in a surprising diversity of transformations. In this review, we present this emerging topic and report the application of chloroferrate ILs as solvents, catalysts or catalytic systems for a variety of chemical processes, with a particular focus on reactions leading to pharmaceutically active compounds or intermediates.
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Cite this article as:
Bica Katharina, Leder Sonja and Gaertner Peter, From Solvent to Sustainable Catalysis - Chloroferrate Ionic Liquids in Synthesis, Current Organic Synthesis 2011; 8 (6) . https://dx.doi.org/10.2174/1570179411108060824
DOI https://dx.doi.org/10.2174/1570179411108060824 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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