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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Samarium Diiodide Catalyzed Aza-Michael Reactions for the Formation of β-Amino Amides

Author(s): Irena Reboule, Sophie Bezzenine-Lafollee, Jacqueline Collin, Richard Gil and Myriam Martin

Volume 7, Issue 2, 2010

Page: [94 - 97] Pages: 4

DOI: 10.2174/157017810790796255

Price: $65

Abstract

Samarium diiodide is an efficient Lewis acid type catalyst for the 1,4-addition of aromatic amines onto α,β- unsaturated N-benzoyl amides affording new β-amino amides. These reactions are compared with similar aza-Michael additions involving α,β-unsaturated-N-acyloxazolidinones.

Keywords: Samarium diiodide, catalysis, amines, Aza-Michael reaction, carbon-nitrogen bond formation


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