Generic placeholder image

Mini-Reviews in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-193X
ISSN (Online): 1875-6298

Hybrid Bidentate Phosphoramidite Ligands in Asymmetric Catalysis

Author(s): Fabien Boeda, Thomas Beneyton and Christophe Crevisy

Volume 5, Issue 2, 2008

Page: [96 - 127] Pages: 32

DOI: 10.2174/157019308784223613

Price: $65

Abstract

Hybrid bidentate phosphoramidite ligands are a recent family of promising phosphorus ligands. The different classes (phosphoramidite-phosphine, phosphoramidite-phosphite, phosphoramidite-phosphinite, phosphoramidite-thioethers, phosphoramidite-amine, phosphoramidite-NHC, phosphoramidite-oxazoline) are presented along with the strategies used to access to these compounds. The main part of the review summarizes the results of the evaluation of these ligands in reactions catalyzed by transition metals/bidentate phosphoramidite ligands, such as hydrogenation, hydroformylation, conjugate addition and Tsuji-Trost reaction.

Keywords: Hybrid bidentate ligands, phosphoramidites, asymmetric catalysis


Rights & Permissions Print Cite
© 2024 Bentham Science Publishers | Privacy Policy