Imino-Ketenimines on an Ortho-Benzylic Scaffold. Nitrogen to Carbon [1,3] Shift of an Ortho-Functionalized Benzyl Group

Title: Imino-Ketenimines on an Ortho-Benzylic Scaffold. Nitrogen to Carbon [1,3] Shift of an Ortho-Functionalized Benzyl Group

Volume: 1 Issue: 4

Author(s): Mateo Alajarin, Angel Vidal and Fulgencio Tovar

Affiliation:

Keywords: imine, ketenimine, nitrile

Abstract: Thermolysis of C,C-disubstituted N-(2-benzylideneamino)benzyl ketenimines in solution provided 2,2-disubstituted 3-(2-benzylideneamino)phenylpropionitriles by [1,3] migration of the substituted benzyl group from nitrogen to carbon in the ketenimine fragment.

Cite this article as:

Alajarin Mateo, Vidal Angel and Tovar Fulgencio, Imino-Ketenimines on an Ortho-Benzylic Scaffold. Nitrogen to Carbon [1,3] Shift of an Ortho-Functionalized Benzyl Group, Letters in Organic Chemistry 2004; 1 (4) . https://dx.doi.org/10.2174/1570178043400398