Abstract
1,2-Oxaphosphetanes are well established intermediate species in the Wittig reaction. Initially, isolable 1,2-oxaphosphetanes represented a source of structural information aimed at supporting mechanistic studies. The evolution of the subject allows the envisaging of stable 1,2-oxaphosphetanes as precursors for the stereoselective formation of olefins.
Keywords: oxaphosphetanes, olefination, wittig, spiro-heterocycles, phosphorus ylides, phosphazenes
Mini-Reviews in Organic Chemistry
Title: Isolable 1,2-Oxaphosphetanes: From Curiosities to Starting Materials for the Synthesis of Olefins
Volume: 1 Issue: 1
Author(s): Fernando Lopez-Ortiz, Jesus Garcia Lopez, Ramon Alvarez Manzaneda and Isidro J. Perez Alvarez
Affiliation:
Keywords: oxaphosphetanes, olefination, wittig, spiro-heterocycles, phosphorus ylides, phosphazenes
Abstract: 1,2-Oxaphosphetanes are well established intermediate species in the Wittig reaction. Initially, isolable 1,2-oxaphosphetanes represented a source of structural information aimed at supporting mechanistic studies. The evolution of the subject allows the envisaging of stable 1,2-oxaphosphetanes as precursors for the stereoselective formation of olefins.
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Cite this article as:
Lopez-Ortiz Fernando, Lopez Garcia Jesus, Manzaneda Alvarez Ramon and Alvarez J. Perez Isidro, Isolable 1,2-Oxaphosphetanes: From Curiosities to Starting Materials for the Synthesis of Olefins, Mini-Reviews in Organic Chemistry 2004; 1 (1) . https://dx.doi.org/10.2174/1570193043488962
DOI https://dx.doi.org/10.2174/1570193043488962 |
Print ISSN 1570-193X |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6298 |
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