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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Synthesis of Luminescent N-Arylcarbazoles by Copper Bronze-Mediated Reaction

Author(s): M. Martinez-Palau, E. Perea, F. Lopez-Calahorra and D. Velasco

Volume 1, Issue 3, 2004

Page: [231 - 237] Pages: 7

DOI: 10.2174/1570178043401261

Price: $65

Abstract

A copper bronze-mediated carbazole arylation reaction under mild reaction conditions is reported. Yields of 9-arylcarbazoles achieved are nearly quantitative and almost independent of the nature of the substitution on the carbazole or the aryl halide. A series of 9-arylcarbazole derivatives have been synthesised and their luminescence studied.

Keywords: 9-arylcarbazole, arylation, copper-bronze catalysis, semiempirical calculations, luminescence


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