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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate

Author(s): M. Shimizu and S. Itohara

Volume 2, Issue 7, 2005

Page: [648 - 651] Pages: 4

DOI: 10.2174/157017805774296902

Price: $65

Abstract

An enolate synthon of alkoxyacetone was regioselectively generated using alkoxyallene oxide and titanium tetraiodide/titanium tetraisopropoxide, and the subsequent conjugate addition reaction with enones gave 4-alkoxy-1,5-diketones in good yields.

Keywords: alkoxyacetone, alkoxyallene oxide, titanium tetraiodide, conjugate addition


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