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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Chiral Di-Imidazolium Molecular Tweezers: Synthesis and Enantioselective Recognition for Amino Acid Derivatives

Author(s): Jing-bo Lan, Ru-gang Xie, Sheng-jin Guo, Qin-xiang Xiang, Jin-song You, Kui Luo and He-yan Jiang

Volume 3, Issue 5, 2006

Page: [363 - 367] Pages: 5

DOI: 10.2174/157017806776611854

Price: $65

Abstract

A series of novel chiral di-imidazolium tweezers were synthesized from L-alanine and L-phenylalanine. These compounds featured two open arms and multipoint binding sites. UV spectroscopic titration experiments showed these chiral di-imidazolium receptors exhibited excellent enantioselective recognition toward L- and D-amino acid derivatives in water or acetonitrile.

Keywords: UV-vis, enantioselective recognition, synthesis, molecular tweezers, Chiral imidazolium


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