Abstract
Alkalides are salts containing alkali metal anions and complexed metal cations. These unusual species discovered by Dye (Dye, J.L.; Andrews, C.W.; Mathews, S.E. J. Phys. Chem., 1975, 79, 3065) are strong reductants of many organic and inorganic compounds. These reactions occur rapidly under mild homogeneous conditions. In this paper we discuss new data concerning the application of potassium potassides selected from the group of alkalides to polymerization processes. Their new and corrected mechanisms for some vinyl and oxacyclic monomers are presented.
Keywords: Diene Monomers, methyl methacrylate polymerization, Lactones, Oxiranes, potassium salts
Current Organic Chemistry
Title: Homogeneous Two-Electron-Transfer Initiation of Anionic Polymerization with Potassium Potassides
Volume: 12 Issue: 7
Author(s): Zbigniew Grobelny, Andrzej Stolarzewicz, Beata Piekarnik and Adalbert Maercker
Affiliation:
Keywords: Diene Monomers, methyl methacrylate polymerization, Lactones, Oxiranes, potassium salts
Abstract: Alkalides are salts containing alkali metal anions and complexed metal cations. These unusual species discovered by Dye (Dye, J.L.; Andrews, C.W.; Mathews, S.E. J. Phys. Chem., 1975, 79, 3065) are strong reductants of many organic and inorganic compounds. These reactions occur rapidly under mild homogeneous conditions. In this paper we discuss new data concerning the application of potassium potassides selected from the group of alkalides to polymerization processes. Their new and corrected mechanisms for some vinyl and oxacyclic monomers are presented.
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Cite this article as:
Grobelny Zbigniew, Stolarzewicz Andrzej, Piekarnik Beata and Maercker Adalbert, Homogeneous Two-Electron-Transfer Initiation of Anionic Polymerization with Potassium Potassides, Current Organic Chemistry 2008; 12 (7) . https://dx.doi.org/10.2174/138527208784245987
DOI https://dx.doi.org/10.2174/138527208784245987 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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