Abstract
Despite their importance in biology and industry, organophosphorus compounds appear quite rarely as an object of supramolecular chemistry studies. Development of synthetic methods in organophosphorus chemistry enabled to design and synthesize compounds of complex structures and thus to develop organophosphorus supramolecular chemistry. In this review, a state-of art showing current progress in design and application of host molecules bearing phosphate, phosphonate, phosphinate or phosphine oxide entities is presented. These structural elements are involved in formation of specific nets of hydrogen bonds and/or electrostatic interactions with complexed molecules (guest molecules) via anionic phosphate or phosphonate residues. Such host molecules are usually designed mostly for a variety of analytical purposes, namely as components of sensors, as extractants, chiral discriminators, membrane carriers etc.
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
Calculation design of covalent/metal organic framework based catalysts
This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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