Porphyrin Based Affinity Interactions: Analytical Applications with Special Reference to Open Tubular Capillary Electrochromatography

Title: Porphyrin Based Affinity Interactions: Analytical Applications with Special Reference to Open Tubular Capillary Electrochromatography

Volume: 1 Issue: 1

Author(s): Zdenek Deyl, Ivan Miksik, Adam Eckhardt, Vaclav Kasicka and Vladimir Kral

Affiliation:

Keywords: oligopyrrolic macrocycles, non-covalent interaction, open tubular capillary electrochromatography, ot-cec, review

Abstract: This review offers a brief summary of results obtained from separations of the sets of biologically relevant compounds (carboxylic acids, amino acids, peptides, nucleotides and organic phosphates) using open tubular capillary electrochromatography (OT-CEC), in which oligopyrrolic macrocycles serve as the modifiers of the inner fused silica capillary wall surface. Types of interactions leading to improved selectivity of the open tubular capillary electrochromatographic systems and/or to the change of the speed of the electroosmotic flow are also discussed. In addition, selected comparative data on the application of oligopyrrolic macrocycles in other analytical methods, particularly chromatographic and spectrometric techniques, are presented.

Cite this article as:

Deyl Zdenek, Miksik Ivan, Eckhardt Adam, Kasicka Vaclav and Kral Vladimir, Porphyrin Based Affinity Interactions: Analytical Applications with Special Reference to Open Tubular Capillary Electrochromatography, Current Analytical Chemistry 2005; 1 (1) . https://dx.doi.org/10.2174/1573411052948451