Abstract
Photooxygenation of non-aromatic heterocycles and cyclic compounds containing non-usual heteroatoms, namely silicon, germanium and tellurium has been reviewed. All three types of photooxygenation (Types I-III) can take place. Moreover the heteroatom can be frequently involved endorsing electron-transfer reactions which turn out to be the main pathways, even in singlet oxygen oxygenation. A vast collection of novel and unexpected products are often formed, sometimes in a stereocontrolled manner.
Keywords: cycloaddition, nucleophilicity, dehydrogenation, biadamantylidene sulfide, conformationally induced electrostatic stabilization
Current Organic Chemistry
Title: Photooxygenation of Non-Aromatic Heterocycles
Volume: 11 Issue: 12
Author(s): M. Rosaria Iesce, F. Cermola and M. Rubino
Affiliation:
Keywords: cycloaddition, nucleophilicity, dehydrogenation, biadamantylidene sulfide, conformationally induced electrostatic stabilization
Abstract: Photooxygenation of non-aromatic heterocycles and cyclic compounds containing non-usual heteroatoms, namely silicon, germanium and tellurium has been reviewed. All three types of photooxygenation (Types I-III) can take place. Moreover the heteroatom can be frequently involved endorsing electron-transfer reactions which turn out to be the main pathways, even in singlet oxygen oxygenation. A vast collection of novel and unexpected products are often formed, sometimes in a stereocontrolled manner.
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Cite this article as:
M. Rosaria Iesce , F. Cermola and M. Rubino , Photooxygenation of Non-Aromatic Heterocycles, Current Organic Chemistry 2007; 11 (12) . https://dx.doi.org/10.2174/138527207781369254
DOI https://dx.doi.org/10.2174/138527207781369254 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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