Abstract
In recent years, diaryliodonium salts have been extensively exploited as green, efficient electrophilic arylation reagents in a large range of organic synthesis. These arylating reagents exhibit relatively high reactivity and good selectivity in many transformations. In this review, the synthetic methods towards diaryliodonium salts are described briefly, and the research progress in arylation reactions by using diaryliodoniums in C-C and carbonheteroatom bond formation, especially in enantioselective C-C bond formation and cascade reactions, in recent ten years is summarized and discussed in detail.
Keywords: Diaryliodonium salts, arylation reaction, nucleophiles, heterocycles, cyclization reaction, cyclic diaryliodonium salt.
Current Organic Chemistry
Title:Recent Progress in Arylation Reactions with Diaryliodonium Salts
Volume: 25 Issue: 11
Author(s): Dan Wang, Qian Li, Mengting Li, Zhengyin Du*Ying Fu*
Affiliation:
- College of Chemistry and Chemical Engineering, Northwest Normal University, 730070 Lanzhou,China
- College of Chemistry and Chemical Engineering, Northwest Normal University, 730070 Lanzhou,China
Keywords: Diaryliodonium salts, arylation reaction, nucleophiles, heterocycles, cyclization reaction, cyclic diaryliodonium salt.
Abstract: In recent years, diaryliodonium salts have been extensively exploited as green, efficient electrophilic arylation reagents in a large range of organic synthesis. These arylating reagents exhibit relatively high reactivity and good selectivity in many transformations. In this review, the synthetic methods towards diaryliodonium salts are described briefly, and the research progress in arylation reactions by using diaryliodoniums in C-C and carbonheteroatom bond formation, especially in enantioselective C-C bond formation and cascade reactions, in recent ten years is summarized and discussed in detail.
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Cite this article as:
Wang Dan , Li Qian , Li Mengting , Du Zhengyin *, Fu Ying *, Recent Progress in Arylation Reactions with Diaryliodonium Salts, Current Organic Chemistry 2021; 25 (11) . https://dx.doi.org/10.2174/1385272825666210512015410
DOI https://dx.doi.org/10.2174/1385272825666210512015410 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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