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Current Nanomaterials

Editor-in-Chief

ISSN (Print): 2405-4615
ISSN (Online): 2405-4623

Research Article

Zeolitic Imidazolate Framework-8 Nanoparticles for Rhodamine B Adsorption

Author(s): Diogo P. Al Rodrigues, Meiry G.F. Rodrigues*, Patrícia F. Tomaz and Tellys L.A. Barbosa

Volume 6, Issue 1, 2021

Published on: 20 November, 2020

Page: [66 - 73] Pages: 8

DOI: 10.2174/2468187310999201120091142

Price: $65

Abstract

Background: Dye removal from effluents is one of the major problems faced in the world. It is a very important environmental issue and it is crucial to solve this problem. In this sense, ZIFs are increasingly becoming important in the environmental area.

Objective: This work presents the synthesis of metalorganic framework Zeolitic Imidazolate Framework- 8 (ZIF-8) nanoparticles, characterization, and then determines the potential to remove Rhodamine B (RhB) from an aqueous solution.

Methods: ZIF-8 was synthesized under solvothermal treatment at 25°C and it was characterized by X-ray diffraction, N2 adsorption-desorption, scanning electron microscopy, and infrared spectroscopy. To evaluate the capacity of the RhB, pH-influence and kinetic studies were carried out. The pseudo first- and second-order kinetic models were used to describe the kinetic data, and the rate constants were evaluated.

Results: ZIF-8 had an average particle size of 47 ± 4.6 nm. The removal percentage increased significantly when the pH was in the range of 7.0-9.0. A pseudo-second-order kinetic of 13.00 mg/g was found for the RhB removal. The adsorption capacity at equilibrium was found to be 11.8 mg/g.

Conclusion: According to the characterization results, the ZIF-8 synthesis was effective and produced a crystalline material. The ZIF-8 presented an affinity to the RhB dye. A pseudo-second- order kinetic model represented well the mechanism of interaction involved during RhB adsorption and ZIF-8.

Keywords: Zeolitic imidazolate framework-8, nanoparticles, solvothermal synthesis, dye removal, Rhodamine B, adsorption, waste water.

Graphical Abstract
[1]
Katheresan V, Kansedo J, Lau SY. Efficiency of various recent wastewater dye removal methods: A review. J Environ Chem Eng 2018; 6: 4676-97.
[http://dx.doi.org/10.1016/j.jece.2018.06.060]
[2]
Pereira L, Alves M. Environmental impact and remediation environmental protection. Strat Sust Develop 2012; 23: 301-12.
[3]
Biswas MM, Taylor KE, Bewtra JK, Biswas N. Enzymatic treatment of sulfonated aromatic amines generated from reductive degradation of reactive azo dyes. Water Environ Res 2007; 79(4): 351-6.
[http://dx.doi.org/10.2175/106143006X111727] [PMID: 17489269]
[4]
Gupta S, Sundarrajan M, Rao KV. Tumor promotion by metanil yellow and malachite green during rat hepatocarcinogenesis is associated with dysregulated expression of cell cycle regulatory proteins. Teratog Carcinog Mutagen 2003; 23(Suppl. 1): 301-12.
[http://dx.doi.org/10.1002/tcm.10056] [PMID: 12616621]
[5]
Mohammadi N, Khani H, Gupta VK, Amereh E, Agarwal S. Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies. J Colloid Interface Sci 2011; 362(2): 457-62.
[http://dx.doi.org/10.1016/j.jcis.2011.06.067] [PMID: 21798549]
[6]
Robati D, Mirza B, Rajabi M, et al. Removal of hazardous dyes-BR 12 and methyl orange using graphene oxide as an adsorbent from aqueous phase. Chem Eng J 2016; 284: 687-97.
[http://dx.doi.org/10.1016/j.cej.2015.08.131]
[7]
Değermenci GD, Değermenci N, Ayvaoğlu V, Durmaz E, Çakır D, Akan E. Adsorption of reactive dyes on lignocellulosic waste; characterization; equilibrium; kinetic and thermodynamic studies. J Clean Prod 2019; 225: 1220-9.
[http://dx.doi.org/10.1016/j.jclepro.2019.03.260]
[8]
Asfaram A, Ghaedi M, Agarwal S, Tyagi I, Gupta VK. Removal of basic dye Auramine-O by ZnS:Cu nanoparticles loaded on activated carbon: optimization of parameters using response surface methodology with central composite design. RSC Advances 2015; 5: 18438-50.
[http://dx.doi.org/10.1039/C4RA15637D]
[9]
Kitagawa S, Kitaura R, Noro S. Functional porous coordination polymers. Angew Chem Int Ed Engl 2004; 43(18): 2334-75.
[http://dx.doi.org/10.1002/anie.200300610] [PMID: 15114565]
[10]
Park KS, Ni Z, Côté AP, et al. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proc Natl Acad Sci USA 2006; 103(27): 10186-91.
[http://dx.doi.org/10.1073/pnas.0602439103] [PMID: 16798880]
[11]
Hasan Z, Jhung SH. Removal of hazardous organics from water using metal-organic frameworks (MOFs): plausible mechanisms for selective adsorptions. J Hazard Mater 2015; 283: 329-39.
[http://dx.doi.org/10.1016/j.jhazmat.2014.09.046] [PMID: 25305363]
[12]
Li S, Chen Y, Pei X, et al. Water Purification: adsorption over metal-organic frameworks. Chin J Chem 2016; 34: 175-85.
[http://dx.doi.org/10.1002/cjoc.201500761]
[13]
Lee YR, Jang MS, Cho HY, Kwon HJ, Kim S, Ahn WS. ZIF-8: a comparison of synthesis methods. Chem Eng J 2015; 271: 276-80.
[http://dx.doi.org/10.1016/j.cej.2015.02.094]
[14]
Pan Y, Liu Y, Zeng G, Zhao L, Lai Z. Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system. Chem Commun (Camb) 2011; 47(7): 2071-3.
[http://dx.doi.org/10.1039/c0cc05002d] [PMID: 21206942]
[15]
Gross AF, Sherman E, Vajo JJ. Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks. Dalton Trans 2012; 41(18): 5458-60.
[http://dx.doi.org/10.1039/c2dt30174a] [PMID: 22406684]
[16]
Cravillon J, Münzer S, Lohmeier S, Feldhoff A, Huber K, Wiebcke M. Rapid room-temperature synthesis and characterization of nanocrystals of a prototypical zeolitic imidazolate framework. Chem Mater 2009; 21: 1410-2.
[http://dx.doi.org/10.1021/cm900166h]
[17]
Cravillon J, Nayuk R, Springer S, Feldhoff A, Huber K, Wiebcke M. Controlling zeolitic imidazolate framework nano- and microcrystal formation: insight into crystal growth by time-resolved in situ static light scattering. Chem Mater 2011; 23: 2130-41.
[http://dx.doi.org/10.1021/cm103571y]
[18]
Fan X, Wang W, Li W, et al. Highly porous ZIF-8 nanocrystals prepared by a surfactant mediated method in aqueous solution with enhanced adsorption kinetics. ACS Appl Mater Interfaces 2014; 6(17): 14994-9.
[http://dx.doi.org/10.1021/am5028346] [PMID: 25109746]
[19]
Tran BL, Chin H, Chang BK, Chiang AST. Dye adsorption in ZIF-8: The importance of external surface area. Microporous Mesoporous Mater 2019; 277: 149-53.
[http://dx.doi.org/10.1016/j.micromeso.2018.10.027]
[20]
Feng Y, Li Y, Xu M, Liu S, Yao J. Fast adsorption of methyl blue on zeolitic imidazolate framework-8 and its adsorption mechanism. RSC Advances 2016; 6: 109608-12.
[http://dx.doi.org/10.1039/C6RA23870J]
[21]
Li Y, Zhou K, He M, Yao J. Synthesis of ZIF-8 and ZIF-67 using mixed-base and their dye adsorption. Microporous Mesoporous Mater 2016; 234: 287-92.
[http://dx.doi.org/10.1016/j.micromeso.2016.07.039]
[22]
Tanaka S, Kida K, Nagaoka T, Ota T, Miyake Y. Mechanochemical dry conversion of zinc oxide to zeolitic imidazolate framework. Chem Commun (Camb) 2013; 49(72): 7884-6.
[http://dx.doi.org/10.1039/c3cc43028f] [PMID: 23715385]
[23]
Tan KB, Vakili M, Horri BA, Poh PE, Abdullah AZ, Salamatinia B. Adsorption of dyes by nanomaterials: Recent developments and adsorption mechanisms. Separ Purif Tech 2015; 150: 229-42.
[http://dx.doi.org/10.1016/j.seppur.2015.07.009]
[24]
Burtch NC, Jasuja H, Walton KS. Water stability and adsorption in metal-organic frameworks. Chem Rev 2014; 114(20): 10575-612.
[http://dx.doi.org/10.1021/cr5002589] [PMID: 25264821]
[25]
Peng J, Guo Y, Xu X, Tang Z. Photophysical performance of a rhodamine-MOF composite structure and its sensing potential for picric acid. J Lumin 2019; 208: 479-87.
[http://dx.doi.org/10.1016/j.jlumin.2018.12.040]
[26]
Du XD, Wang CC, Liu JG, et al. Extensive and selective adsorption of ZIF-67 towards organic dyes: performance and mechanism. J Colloid Interface Sci 2017; 506: 437-41.
[http://dx.doi.org/10.1016/j.jcis.2017.07.073] [PMID: 28753488]
[27]
Tien C. Adsorption calculation and modeling. Boston: Butteworth-Heinemann 1994.
[28]
Sing KSW, Everett DH, Haul RAW, et al. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 1985; 57: 603-19.
[http://dx.doi.org/10.1351/pac198557040603]
[29]
Nune SK, Thallapally PK, Dohnalkova A, Wang C, Liu J, Exarhos GJ. Synthesis and properties of nano zeolitic imidazolate frameworks. Chem Commun (Camb) 2010; 46(27): 4878-80.
[http://dx.doi.org/10.1039/c002088e] [PMID: 20585703]
[30]
Khan NA, Jung BK, Hasan Z, Jhung SH. Adsorption and removal of phthalic acid and diethyl phthalate from water with zeolitic imidazolate and metal-organic frameworks. J Hazard Mater 2015; 282: 194-200.
[http://dx.doi.org/10.1016/j.jhazmat.2014.03.047] [PMID: 24726184]
[31]
Anandkumar J, Mandal B. Adsorption of chromium(VI) and Rhodamine B by surface modified tannery waste: kinetic, mechanistic and thermodynamic studies. J Hazard Mater 2011; 186(2-3): 1088-96.
[http://dx.doi.org/10.1016/j.jhazmat.2010.11.104] [PMID: 21168268]
[32]
Gao Y, Wang Y, Zhang H. Removal of Rhodamine B with Fe-supported bentonite as heterogenous photo-fenton catalyst under visible irradiation. Appl Catal B 2015; 178: 29-36.
[http://dx.doi.org/10.1016/j.apcatb.2014.11.005]
[33]
Zhang J, Yan X, Hu X, Feng R, Zhou V. Direct carbonization of Zn/Co zeolitic imidazolate frameworks for efficient adsorption of Rhodamine B. Chem Eng J 2018; 347: 640-7.
[http://dx.doi.org/10.1016/j.cej.2018.04.132]
[34]
Inbaraj BS, Sulochana N. Use of jackfruit peel carbon (JPC) for adsorption of rhodamine-B, a basic dye from aqueous aqueous solution. Indian J Chem Technol 2006; 13: 17-23.
[35]
Zhou ML, Martin G. Adsorption kinetics modelling in batch reactor onto activated carbon by the model HSDM. Environ Technol 1995; 16: 827-38.
[http://dx.doi.org/10.1080/09593331608616321]
[36]
Cheung CW, Porter JF, Mckay G. Sorption kinetic analysis for the removal of cadmium ions from effluents using bone char. Water Res 2001; 35(3): 605-12.
[http://dx.doi.org/10.1016/S0043-1354(00)00306-7] [PMID: 11228955]
[37]
Wu FC, Tseng RL, Juang RS. Adsorption of dyes and phenols from water on the activated carbons prepared from corncob wastes. Environ Technol 2001; 22(2): 205-13.
[http://dx.doi.org/10.1080/09593332208618296] [PMID: 11349379]
[38]
Özacar M, Şengil İA. Adsorption of reactive dyes on calcined alunite from aqueous solutions. J Hazard Mater 2003; 98(1-3): 211-24.
[http://dx.doi.org/10.1016/S0304-3894(02)00358-8] [PMID: 12628789]
[39]
Ho YS, McKay G. Kinetic models for the sorption of dye from aqueous solution by wood. Trans Inst Chem Eng 1998; 76: 183-91.
[http://dx.doi.org/10.1205/095758298529326]
[40]
Wang Y, Dai X, Zhan Y, Ding X, Wang M, Wang X. In situ growth of ZIF-8 nanoparticles on chitosan to form the hybrid nanocomposites for high-efficiency removal of Congo Red. Int J Biol Macromol 2019; 137: 77-86.
[http://dx.doi.org/10.1016/j.ijbiomac.2019.06.195] [PMID: 31254578]

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