Applications of Selectfluor for the Oxidation of Sulfides, Urazoles and Acohols Under the Solvent-free Conditions

(E-pub Ahead of Print)

Author(s): Gholamabbas Chehardoli*, Mohammad Ali Zolfigo, Shadpour Mallakpour

Journal Name: Current Organocatalysis

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Abstract:

Selectfluor acts as a safe and efficient reagent for the oxidation of urazoles, alcohols and also sulfides via releasing the electrophile F under the solvent-free conditions. In room temperature, this reagent cannot oxidize the substrates alone and requires KBr as the catalyst. In the proposed mechanism, Selectfluor converts the Br- to the Br-F and the lone-pair electron of substrates attack to Br-F to perform the oxidation reaction. This procedure offers some advantages; for example short reaction time, simple work-up, good yield and matching with some green chemistry approaches.

Keywords: Selectfluor, oxidation, urazoles, alcohols, sulfides.

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(E-pub Ahead of Print)
DOI: 10.2174/2213337207999200909114816
Price: $95

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