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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Review Article

Tunable Calcium-Apatites as Solid Catalysts for Classical Organic Reactions

Author(s): Michel Gruselle and Kaia Tonsuaadu

Volume 21, Issue 8, 2017

Page: [688 - 697] Pages: 10

DOI: 10.2174/1385272821666161219155302

Price: $65

Abstract

Apatites, minerals that are involved in numerous applications in chemistry, biochemistry and medicine have shown important catalytic properties and are emerging as powerful catalysts in various organic reactions (oxidation, C-C bond formation, cycloaddition, N-Arylation, epoxidation, water gas shift reaction, hydroformylation, CH4 coupling reaction….). Apatites, in which the composition and surface properties can be tuned by replacing anions or cations in their structures, leading to a large spectrum of compositions, can also be used as macroligands to support catalytic active centers. In this review we emphasize the creation of a large variety of modified apatites, and describe their structures and properties as well as their catalytic activities.

Keywords: Calcium-apatite, modified apatites, catalysis.

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