Ring Expansion of N-H Ketoaziridines to Five and Six-Membered NHeterocycles

Title:Ring Expansion of N-H Ketoaziridines to Five and Six-Membered NHeterocycles

Volume: 12 Issue: 4

Author(s): Heshmat A. Samimi

Affiliation:

Keywords: Ketoaziridine, rearrangement, ring expansion, stereo- and regioselectivity.

Abstract: This review reports the chemistry of 2,3-disubstituted N-H aziridines to Five and sixmemberd N-heterocycles. Emphasis will be put on the aspects of stereo- and regioselectivity of appropriate reactions such as 1,3-dipolar, ring expansion reactions as well as C-C or C-N bond cleavage of aziridine ring.

Cite this article as:

Samimi A. Heshmat, Ring Expansion of N-H Ketoaziridines to Five and Six-Membered NHeterocycles, Mini-Reviews in Organic Chemistry 2015; 12 (4) . https://dx.doi.org/10.2174/1570193X12666150930224129