Abstract
The reactivity in the confined spaces of zeolites, metal-organic frameworks, cage compounds and macrocycles differ in many aspects from those conducted in bulk solution. Cases of altered regioselectivity, enhanced stability and accelerated substrate reactivity are presented within the context of non-covalent interactions between host and guest molecules, which define much of supramolecular chemistry, being unique and imparting highly useful properties that are of interest for their intellectual merit as well as their immense commercial value.
Keywords: Catalysis, metal-organic frameworks, supramolecular, zeolite.
Current Organic Chemistry
Title:The Chemistry of Confined Spaces
Volume: 18 Issue: 15
Author(s): Jenny Jiou, Krishnakanth Chiravuri, Aditya Gudapati and Jeremiah J. Gassensmith
Affiliation:
Keywords: Catalysis, metal-organic frameworks, supramolecular, zeolite.
Abstract: The reactivity in the confined spaces of zeolites, metal-organic frameworks, cage compounds and macrocycles differ in many aspects from those conducted in bulk solution. Cases of altered regioselectivity, enhanced stability and accelerated substrate reactivity are presented within the context of non-covalent interactions between host and guest molecules, which define much of supramolecular chemistry, being unique and imparting highly useful properties that are of interest for their intellectual merit as well as their immense commercial value.
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Cite this article as:
Jiou Jenny, Chiravuri Krishnakanth, Gudapati Aditya and Gassensmith J. Jeremiah, The Chemistry of Confined Spaces, Current Organic Chemistry 2014; 18 (15) . https://dx.doi.org/10.2174/1385272819666140514005254
DOI https://dx.doi.org/10.2174/1385272819666140514005254 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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