Abstract
A series of sulfides was successfully synthesized from nitroarenes by SNAr reaction via elimination of a nitro or phenylsulfonyl group. The SNAr reaction mechanism is found to depend on the position and type of substituents, and the effect of two-electron withdrawing groups was also examined.
Keywords: Sulfide, SNAr reaction, nitro group, aryl disulfide.
Current Organic Synthesis
Title:Synthesis of Asymmetric Diaryl Sulfides by SNAr Reaction of Substituted Nitrobenzene with Aryl Disulfides
Volume: 10 Issue: 6
Author(s): Naoki Enjo, Rong Lu and Tetsuo Miyakoshi
Affiliation:
Keywords: Sulfide, SNAr reaction, nitro group, aryl disulfide.
Abstract: A series of sulfides was successfully synthesized from nitroarenes by SNAr reaction via elimination of a nitro or phenylsulfonyl group. The SNAr reaction mechanism is found to depend on the position and type of substituents, and the effect of two-electron withdrawing groups was also examined.
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Cite this article as:
Enjo Naoki, Lu Rong and Miyakoshi Tetsuo, Synthesis of Asymmetric Diaryl Sulfides by SNAr Reaction of Substituted Nitrobenzene with Aryl Disulfides, Current Organic Synthesis 2013; 10 (6) . https://dx.doi.org/10.2174/157017941006140206105221
DOI https://dx.doi.org/10.2174/157017941006140206105221 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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