Abstract
Different cross-coupling reactions for the formation of biologically important motifs and intermediates in organic synthesis using various suitable copper catalysts are reviewed. These include C-C, C-N, C-O, C-S heteroatom bond forming, cyclization and other miscellaneous reactions catalyzed by elemental copper, copper salts, CuI, Cu (OTf)2, CuBr, Cu2O etc. The use of copper reagents instead of palladium catalysts and ligands seems to be advantageous from the commercial point of view. The methods described herein afford the products in excellent yield without using expensive and moisture/air sensitive palladium catalysts, ligands and reagents.
Keywords: Copper catalysts, Cross coupling reactions, Ligands.
Mini-Reviews in Organic Chemistry
Title:Application Progress of Recent Advances in Some Copper Catalyzed Coupling Reactions
Volume: 10 Issue: 3
Author(s): Sunil U. Tekale, Vivekanand B. Jadhav, Vijay P. Pagore, Sushma S. Kauthale, Digambar D. Gaikwad and Rajendra P. Pawar
Affiliation:
Keywords: Copper catalysts, Cross coupling reactions, Ligands.
Abstract: Different cross-coupling reactions for the formation of biologically important motifs and intermediates in organic synthesis using various suitable copper catalysts are reviewed. These include C-C, C-N, C-O, C-S heteroatom bond forming, cyclization and other miscellaneous reactions catalyzed by elemental copper, copper salts, CuI, Cu (OTf)2, CuBr, Cu2O etc. The use of copper reagents instead of palladium catalysts and ligands seems to be advantageous from the commercial point of view. The methods described herein afford the products in excellent yield without using expensive and moisture/air sensitive palladium catalysts, ligands and reagents.
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Cite this article as:
Tekale U. Sunil, Jadhav B. Vivekanand, Pagore P. Vijay, Kauthale S. Sushma, Gaikwad D. Digambar and Pawar P. Rajendra, Application Progress of Recent Advances in Some Copper Catalyzed Coupling Reactions, Mini-Reviews in Organic Chemistry 2013; 10 (3) . https://dx.doi.org/10.2174/1570193X11310030007
DOI https://dx.doi.org/10.2174/1570193X11310030007 |
Print ISSN 1570-193X |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6298 |
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