Bis-quinolizidine Complexes: Structure, Spectroscopic Properties and Theoretical Calculations

Title:Bis-quinolizidine Complexes: Structure, Spectroscopic Properties and Theoretical Calculations

Volume: 10 Issue: 3

Author(s): Beata Jasiewicz and Tomasz Pospieszny

Affiliation:

Keywords: Bis-quinolizidine N-oxides, theoretical calculations, metal complexes, sparteine derivatives, spectroscopic properties, x-ray structure.

Abstract: Coordination compounds based on bis-quinolizidine derivatives as ligands are described from the viewpoint of their spectroscopic and structural properties. The metal ligand ability of C2 substituted sparteines and bis-quinolizidine Noxides is discussed in order to establish how far the presence of a substituent at α position to the nitrogen atom, involved in the formation of metal complexes or N-oxide function, influences the course of the complexation reaction and geometry of the complexes. The results are confronted with theoretical calculations. Potential pharmacological properties of selected complexes are also determined.

Cite this article as:

Jasiewicz Beata and Pospieszny Tomasz, Bis-quinolizidine Complexes: Structure, Spectroscopic Properties and Theoretical Calculations, Mini-Reviews in Organic Chemistry 2013; 10 (3) . https://dx.doi.org/10.2174/1570193X11310030002