Abstract
Herein, we describe the synthesis of a series of rac-N,N'-dibenzylpropane-2-aryl-substituted imidazolidines prepared from the corresponding aromatic aldehydes and two N,N'-dibenzylpropane-1,2-diamines, namely rac-N,N'-dibenzylpropane-1,2-diamine 3a and rac-2,2'-[propane-1,2-diylbis(iminomethanediyl)]diphenol 3b, produced by the NaBH4 reduction of the corresponding diimines of benzaldehyde and salicylaldehyde.
Keywords: Bridged bis(phenol), 5-endo-trig, Imidazolidines, Salan, Stereoselectivity, vic-1, 2-diamines.
Current Organic Chemistry
Title:Synthesis and Characterization of Novel Chiral 1,2,3,4-tetrasubstituted Imidazolidines Derived from rac-1,2-propanediamine
Volume: 17 Issue: 24
Author(s): Augusto Rivera, Lorena Cárdenas and Jaime Ríos-Motta
Affiliation:
Keywords: Bridged bis(phenol), 5-endo-trig, Imidazolidines, Salan, Stereoselectivity, vic-1, 2-diamines.
Abstract: Herein, we describe the synthesis of a series of rac-N,N'-dibenzylpropane-2-aryl-substituted imidazolidines prepared from the corresponding aromatic aldehydes and two N,N'-dibenzylpropane-1,2-diamines, namely rac-N,N'-dibenzylpropane-1,2-diamine 3a and rac-2,2'-[propane-1,2-diylbis(iminomethanediyl)]diphenol 3b, produced by the NaBH4 reduction of the corresponding diimines of benzaldehyde and salicylaldehyde.
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Cite this article as:
Rivera Augusto, Cárdenas Lorena and Ríos-Motta Jaime, Synthesis and Characterization of Novel Chiral 1,2,3,4-tetrasubstituted Imidazolidines Derived from rac-1,2-propanediamine, Current Organic Chemistry 2013; 17 (24) . https://dx.doi.org/10.2174/13852728113179990027
DOI https://dx.doi.org/10.2174/13852728113179990027 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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