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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Synthesis and Characterization of Novel Chiral 1,2,3,4-tetrasubstituted Imidazolidines Derived from rac-1,2-propanediamine

Author(s): Augusto Rivera, Lorena Cárdenas and Jaime Ríos-Motta

Volume 17, Issue 24, 2013

Page: [3073 - 3077] Pages: 5

DOI: 10.2174/13852728113179990027

Price: $65

Abstract

Herein, we describe the synthesis of a series of rac-N,N'-dibenzylpropane-2-aryl-substituted imidazolidines prepared from the corresponding aromatic aldehydes and two N,N'-dibenzylpropane-1,2-diamines, namely rac-N,N'-dibenzylpropane-1,2-diamine 3a and rac-2,2'-[propane-1,2-diylbis(iminomethanediyl)]diphenol 3b, produced by the NaBH4 reduction of the corresponding diimines of benzaldehyde and salicylaldehyde.

Keywords: Bridged bis(phenol), 5-endo-trig, Imidazolidines, Salan, Stereoselectivity, vic-1, 2-diamines.


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