Zinc-Mediated Chain Extension Reaction of o-Phenolic-l,3-diketone to o- Phenolic-l,4-diketone

Title:Zinc-Mediated Chain Extension Reaction of o-Phenolic-l,3-diketone to o- Phenolic-l,4-diketone

Volume: 10 Issue: 3

Author(s): Hui-Fang Liu, Ling-Guo Meng, Xiao-Li Hao, Qiao- Lin, Jian-Fa Li and Song Xue

Affiliation:

Keywords: o-Phenolic-l, 3-diketones, organozinc reagents, trifluoroacetic acid, diiodomethane, chain extension reaction, ophenolic- l, 4-diketones.

Abstract: A simple methodology has been developed for the synthesis of o-phenolic-l,4-diketones from the o-phenolicl, 3-diketones. The reaction performed in the presence of organozinc reagents under mild conditions afforded the products l,4-diketones in moderate yields.

Cite this article as:

Liu Hui-Fang, Meng Ling-Guo, Hao Xiao-Li, Lin Qiao-, Li Jian-Fa and Xue Song, Zinc-Mediated Chain Extension Reaction of o-Phenolic-l,3-diketone to o- Phenolic-l,4-diketone, Letters in Organic Chemistry 2013; 10 (3) . https://dx.doi.org/10.2174/1570178611310030014