Abstract
Ionic liquids are often used together with dichloromethane in different reactions. This combination can be problematic because the use of ionic liquids with a carboxylic acid as an anion and dichloromethane can lead to the formation of methylene diesters. The reaction of trioctylmethylammonium benzoate with dichloromethane was studied, where the ionic liquid acted as reactant, solvent and catalyst. The molecular structure of methylene dibenzoate was determined by X-ray crystallography.
Keywords: Dichloromethane, Ionic liquids, Metilenedibenzoates, Synthesis, X-ray Diffraction, Trioctylmethylammonium benzoate, Methylene dibenzoate, Transesterification, Cyclohexane, Biphasic hydrogenation systems
Current Organic Chemistry
Title:A New Route for the Synthesis of Methylene Dibenzoate by Using An Ionic Liquid
Volume: 17 Issue: 1
Author(s): Natalya V. Likhanova, Irina V. Lijanova, Laura P. Morelos Alvarado, Marcos Martinez Garcia, Simon Hernandez-Ortega and Octavio Olivares Xometl
Affiliation:
Keywords: Dichloromethane, Ionic liquids, Metilenedibenzoates, Synthesis, X-ray Diffraction, Trioctylmethylammonium benzoate, Methylene dibenzoate, Transesterification, Cyclohexane, Biphasic hydrogenation systems
Abstract: Ionic liquids are often used together with dichloromethane in different reactions. This combination can be problematic because the use of ionic liquids with a carboxylic acid as an anion and dichloromethane can lead to the formation of methylene diesters. The reaction of trioctylmethylammonium benzoate with dichloromethane was studied, where the ionic liquid acted as reactant, solvent and catalyst. The molecular structure of methylene dibenzoate was determined by X-ray crystallography.
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Cite this article as:
V. Likhanova Natalya, V. Lijanova Irina, P. Morelos Alvarado Laura, Martinez Garcia Marcos, Hernandez-Ortega Simon and Olivares Xometl Octavio, A New Route for the Synthesis of Methylene Dibenzoate by Using An Ionic Liquid, Current Organic Chemistry 2013; 17 (1) . https://dx.doi.org/10.2174/138527213805289178
DOI https://dx.doi.org/10.2174/138527213805289178 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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