Abstract
In this article we discuss synthetic routes to organic conjugated oligomers and polymers bearing triple C-C bonds that have been recently developed in our laboratories, based on Pd-catalyzed Csp-Csp2 coupling reactions. Experimental protocols have been tuned to face synthetic challenges such as the presence in the main conjugated backbone of multifunctional substituents or uncommon conjugated units. The relevance of the obtained products in terms of properties and applications is also shortly mentioned.
Keywords: Aryleneethynylenes, conjugated oligomers, conjugated polymers, cross-coupling, Sonogashira reaction, triple C-C bonds, chiral polymers, biopolymers, organic electronics, thiol, molecular wires, self-assembly, molecular electronics, anthraquinone, norbornadiene, photoisomerization.
Current Organic Synthesis
Title:Synthesis of Functionalized Aryleneethynylene Oligomers and Polymers for Organic Electronics by Pd-Catalyzed Coupling Reactions
Volume: 9 Issue: 6
Author(s): Alessandra Operamolla, Roberta Ragni, Omar H. Omar, Giuliano Iacobellis, Antonio Cardone, Francesco Babudri and Gianluca M. Farinola
Affiliation:
Keywords: Aryleneethynylenes, conjugated oligomers, conjugated polymers, cross-coupling, Sonogashira reaction, triple C-C bonds, chiral polymers, biopolymers, organic electronics, thiol, molecular wires, self-assembly, molecular electronics, anthraquinone, norbornadiene, photoisomerization.
Abstract: In this article we discuss synthetic routes to organic conjugated oligomers and polymers bearing triple C-C bonds that have been recently developed in our laboratories, based on Pd-catalyzed Csp-Csp2 coupling reactions. Experimental protocols have been tuned to face synthetic challenges such as the presence in the main conjugated backbone of multifunctional substituents or uncommon conjugated units. The relevance of the obtained products in terms of properties and applications is also shortly mentioned.
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Cite this article as:
Operamolla Alessandra, Ragni Roberta, Omar H. Omar, Iacobellis Giuliano, Cardone Antonio, Babudri Francesco and Farinola M. Gianluca, Synthesis of Functionalized Aryleneethynylene Oligomers and Polymers for Organic Electronics by Pd-Catalyzed Coupling Reactions, Current Organic Synthesis 2012; 9 (6) . https://dx.doi.org/10.2174/157017912803901655
DOI https://dx.doi.org/10.2174/157017912803901655 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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Organic synthesis is a fundamental discipline in chemistry, crucial for the creation of complex molecules with diverse applications in pharmaceuticals, materials science, and beyond. However, the process of designing efficient synthetic routes for target molecules remains challenging. Chemical graph theory, a branch of theoretical chemistry, offers powerful tools for understanding ...read more
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