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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

Efficient Synthesis of Diacetoxyiodoarenes via Intramolecular Rearrangement

Author(s): De-Jun Zhou*, Yang-Yang Zhai, Ling-Pu Meng, Wei-Wei Song, Xiao Liu and Shu-Qiang Yin*

Volume 16, Issue 11, 2019

Page: [911 - 914] Pages: 4

DOI: 10.2174/1570178616666181203142445

Price: $65

Abstract

This study introduces a concise and efficient method for preparing diacetoxyiodoarenes from the corresponding iodoarenes. In the presence of acetic anhydride, iodoarenes were oxidized to diacetoxyiodoarenes by sodium perborate in acetic acid under argon protection at 55°C in ideal yields. Through this method, 10 diacetoxyiodoarenes were obtained smoothly.

Keywords: Diacetoxyiodoarenes, acetic anhydride, sodium perborate, intramolecular rearrangement, ideal yields, iodoarenes.

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