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Current Organic Chemistry


ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Research Article

Amidoselenation of Alkenes Yielding the β-Amido-selenides through a Radical Pathway

Author(s): Feng Zhao, Ting Sun, Zhenhua Liu, Kai Sun, Chong Zhang and Xin Wang*

Volume 22, Issue 6, 2018

Page: [613 - 618] Pages: 6

DOI: 10.2174/2215081107666180123144818

Price: $65


An efficient protocol for the intermolecular amidoselenation of alkenes with diphenyl diselenides and acetonitrile has been developed that affords a series of β-amidoselenides in high yields under mild conditions. The preliminary experimental results support the involvement of active benzyl radical species, and a radical pathway was therefore proposed for the reaction.

Keywords: Alkenes, amidoselenation, radical, difunctionalization, β-amido-selenides, transformation.

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