Abstract
This review describes the chemistry of 1,2,5- and 1,4,5-thiadiazepines. The investigated heterocycles are monocyclic and fused 1,2,5- and 1,4,5-thiadiazepines. The different sections cover: structural elucidation "spectroscopy", reactivity of substituents attached to ring carbon and nitrogen atoms, synthesis of monocyclic and fused heterocycles incorporated 1,2,5- and 1,4,5-thiadiazepine moiety. Nitrogen and sulfur atoms of thiadiazepine ring system have the ability to donate the electrons pairs in order to form coordination bonds forming different complexes. The aim of this review is to discuss the chemistry of title compounds up till now. The reaction mechanisms are described and discussed, as well as, the biological applications of the target compounds.
Keywords: 1, 2, 5-Thiadiazepines, 1, 4, 5-thiadiazepines, spectroscopic data, reactivity, synthetic methods, biological importance.
Current Organic Chemistry
Title:Seven-membered Rings with Three Heteroatoms: Chemistry of 1,2,5- and 1,4,5- thiadiazepines
Volume: 22 Issue: 4
Author(s): Basak Dogru Mert*Khaled M. Elattar
Affiliation:
- Higher School of Health, Mardin Artuklu University, 47200, Mardin,Turkey
Keywords: 1, 2, 5-Thiadiazepines, 1, 4, 5-thiadiazepines, spectroscopic data, reactivity, synthetic methods, biological importance.
Abstract: This review describes the chemistry of 1,2,5- and 1,4,5-thiadiazepines. The investigated heterocycles are monocyclic and fused 1,2,5- and 1,4,5-thiadiazepines. The different sections cover: structural elucidation "spectroscopy", reactivity of substituents attached to ring carbon and nitrogen atoms, synthesis of monocyclic and fused heterocycles incorporated 1,2,5- and 1,4,5-thiadiazepine moiety. Nitrogen and sulfur atoms of thiadiazepine ring system have the ability to donate the electrons pairs in order to form coordination bonds forming different complexes. The aim of this review is to discuss the chemistry of title compounds up till now. The reaction mechanisms are described and discussed, as well as, the biological applications of the target compounds.
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Cite this article as:
Mert Dogru Basak *, Elattar M. Khaled , Seven-membered Rings with Three Heteroatoms: Chemistry of 1,2,5- and 1,4,5- thiadiazepines, Current Organic Chemistry 2018; 22 (4) . https://dx.doi.org/10.2174/1385272821666170920163512
DOI https://dx.doi.org/10.2174/1385272821666170920163512 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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