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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Study on the Fluorine-Containing Reactive Intermediates and Their Application in the Organic Synthesis

Author(s): S. Z. Zhu and P. He

Volume 8, Issue 2, 2004

Page: [97 - 112] Pages: 16

DOI: 10.2174/1385272043486034

Price: $65

Abstract

This review deals with recent progress concerning the preparations, reactions, mechanisms and synthetic applications of some precursor compounds of the fluorine-containing reactive intermediates, such as phenyliodonium bis (perfluoro alkanesulfonyl) methides, PhI+--C(SO2Rf)2; perfluoroalkanesulfonyl azides, RfSO2N3 N,N-dichloro perfluoroalkanesulfonyl amides, RfSO2NCl2, aryldiazonium bis(perfluoro alkanesulfonyl) methides, ArN2 +--CH(SO2Rf)2, aryldiazonium bis(perfluoroalkanesulfonyl) imides, ArN2 +--N(SO2Rf)2 N-sulfinyl per- (or) polyfluoroalkanesulfonyl amides, RfSO2N=S=O, N-sulfinyl per- (or) polyfluorophenylaniline, ArFN=S=O. Under mild reaction conditions they react readily with many organic reagents to give various fluorine-containing products.

Keywords: Fluorine, phenyliodonium, polyfluorophenylaniline, N-sulfinyl


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