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Current Organic Synthesis

Editor-in-Chief

ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Selective Oxidation of Sulfides to Sulfoxides with Tert-Butylnitrite as an Alternative Oxidant

Author(s): Bing Yu, Zhen-Feng Diao, An-Hua Liu, Xu Han, Bin Li, Liang-Nian He and Xiang-Ming Liu

Volume 11 , Issue 1 , 2014

Page: [156 - 160] Pages: 5

DOI: 10.2174/1570179411999140304142430

Price: $65

Abstract

Tert-butylnitrite was proved to be an efficient oxidant for the selective oxidation of sulfides to sulfoxides. The reaction was promoted by Fe(NO3)3·9H2O under mild conditions and various substrates were effectively converted into the corresponding sulfoxides in good yields and excellent selectivity.

Keywords: Fe-promoted, oxidation, selectivity, sulfide, sulfoxide, Tert-Butylnitrite.


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