Abstract
Immobilization of ruthenium metathesis catalysts on solid supports has attracted much attention in recent years since it opens up the possibility for easy catalyst–product separation and catalyst reuse as well as reduction of the residual ruthenium content in the organic product. The state of the art on immobilization of ruthenium based metathesis initiators on solid supports is surveyed in this review. In addition, a comparison of the performance of the heterogenized catalysts with homogeneous analogues is made.
Keywords: Alkylidene, Immobilization, Inorganic supports, Heterogeneous catalysis, Olefin Metathesis, polymeric supports, ruthenium carbenes, ruthenium.
Current Organic Chemistry
Title:Solid Supported Ruthenium Complexes for Olefin Metathesis
Volume: 17 Issue: 22
Author(s): Fatma B. Hamad, Cheng Kai, Yuan Cai, Yu Xie, Yin Lu, Fu Ding, Yaguan Sun and Francis Verpoort
Affiliation:
Keywords: Alkylidene, Immobilization, Inorganic supports, Heterogeneous catalysis, Olefin Metathesis, polymeric supports, ruthenium carbenes, ruthenium.
Abstract: Immobilization of ruthenium metathesis catalysts on solid supports has attracted much attention in recent years since it opens up the possibility for easy catalyst–product separation and catalyst reuse as well as reduction of the residual ruthenium content in the organic product. The state of the art on immobilization of ruthenium based metathesis initiators on solid supports is surveyed in this review. In addition, a comparison of the performance of the heterogenized catalysts with homogeneous analogues is made.
Export Options
About this article
Cite this article as:
Hamad B. Fatma, Kai Cheng, Cai Yuan, Xie Yu, Lu Yin, Ding Fu, Sun Yaguan and Verpoort Francis, Solid Supported Ruthenium Complexes for Olefin Metathesis, Current Organic Chemistry 2013; 17 (22) . https://dx.doi.org/10.2174/13852728113179990111
DOI https://dx.doi.org/10.2174/13852728113179990111 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
Calculation design of covalent/metal organic framework based catalysts
This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
Related Journals
- Author Guidelines
- Graphical Abstracts
- Fabricating and Stating False Information
- Research Misconduct
- Post Publication Discussions and Corrections
- Publishing Ethics and Rectitude
- Increase Visibility of Your Article
- Archiving Policies
- Peer Review Workflow
- Order Your Article Before Print
- Promote Your Article
- Manuscript Transfer Facility
- Editorial Policies
- Allegations from Whistleblowers
- Announcements