Abstract
While iron oxide nanoparticles enjoy rich applications as catalysts, solid supports, and magnets, the use of their reduced and much less stable counterparts in the oxidation state zero is still at an infant stage. This minireview summarizes recent developments in the area of such metallic iron(0) nanoparticles. A major emphasis is laid on the controlled synthesis of small particles (mostly < 50 nm) and their application as catalysts to organic synthesis. Initial catalytic studies include hydrogenation and cross-coupling reactions which clearly indicate the great potential of iron nanoparticles to rival the efficiency of nickel and palladium catalysts.
Keywords: Iron, Nanoparticles, Catalysis, Cross-coupling, Reduction
Current Organic Chemistry
Title:Iron(0) Nanoparticle Catalysts in Organic Synthesis
Volume: 17 Issue: 4
Author(s): Alice Welther and Axel Jacobi von Wangelin
Affiliation:
Keywords: Iron, Nanoparticles, Catalysis, Cross-coupling, Reduction
Abstract: While iron oxide nanoparticles enjoy rich applications as catalysts, solid supports, and magnets, the use of their reduced and much less stable counterparts in the oxidation state zero is still at an infant stage. This minireview summarizes recent developments in the area of such metallic iron(0) nanoparticles. A major emphasis is laid on the controlled synthesis of small particles (mostly < 50 nm) and their application as catalysts to organic synthesis. Initial catalytic studies include hydrogenation and cross-coupling reactions which clearly indicate the great potential of iron nanoparticles to rival the efficiency of nickel and palladium catalysts.
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Cite this article as:
Welther Alice and Jacobi von Wangelin Axel, Iron(0) Nanoparticle Catalysts in Organic Synthesis, Current Organic Chemistry 2013; 17 (4) . https://dx.doi.org/10.2174/1385272811317040003
DOI https://dx.doi.org/10.2174/1385272811317040003 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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