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Current Organic Synthesis


ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Recent Advancement of the thio-Claisen Rearrangement

Author(s): Krishna C. Majumdar, Srikanta Samanta, Buddhadeb Chattopadhyay and Nilasish Pal

Volume 9 , Issue 6 , 2012

Page: [851 - 872] Pages: 22

DOI: 10.2174/157017912803901682

Price: $65


This brief review deals with the recent progress in the implimentation of thio-Claisen rearrangement in synthetic organic chemistry. Thio-Claisen rearrangement has been utilized for the synthesis of many heterocyclic moieties of biological significance. Stereoselectivity of the thio-Claisen rearrangement has also been discussed. This short report mainly covers the literature published during 2003 onwards.

Keywords: Thio-Claisen rearrangement, thermal Claisen-rearrangement, catalyzed-Claisen rearrangement, asymmetric rearrangement, sulfur heterocycles, regioselective synthesis, stereoselective synthesis, electrocyclization, [3, 3]-sigmatropic shift, cyclodextrin, dihydroflustramine C, sequential Claisen rearrangement, [Rh2((S)-tbsp)4].

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