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Letters in Organic Chemistry


ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Pd/C-Catalyzed Cross-Coupling of Arenediazonium Salts with Potassium Aryltrifluoroborates

Author(s): Lee S. Varnedoe, Brad D. Angel, Joshua L. McClellan and James M. Hanna Jr.

Volume 7, Issue 1, 2010

Page: [1 - 6] Pages: 6

DOI: 10.2174/157017810790533968

Price: $65


A convenient protocol for the synthesis of biaryls from arenediazonium salts and potassium aryltrifluoroborates in refluxing methanol catalyzed by Pd/C is described. The protocol is simple to execute and gives moderate to high yields of cross-coupling products in most cases.

Keywords: Diazonium salts, potassium aryltrifluoroborates, Pd/C, cross-coupling, biaryl synthesis, suzuki-miyaura

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