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Current Organic Synthesis

Editor-in-Chief

ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Rhodium(I) N-Heterocyclic Carbene Complexes as Catalysts for Hydroformylation of Olefins: An Overview

Author(s): Ana R. Almeida, Andreia F. Peixoto, Mario J. F. Calvete, Pedro M. P. Gois and Mariette M. Pereira

Volume 8 , Issue 5 , 2011

Page: [764 - 775] Pages: 12

DOI: 10.2174/157017911796957339

Price: $65

Abstract

The present state of art on the application of carbene-rhodium complexes as stable catalysts for hydroformylation reaction is described. A critical analysis of the influence of pressure and temperature on the hydroformylation of non-modified rhodium complexes and those ones described in the presence of carbenes is also done. Finally, a set of experiments using NHCs prepared by us at different reactions conditions is presented and discussed.

Keywords: Aliphatic olefins, hydroformylation, rhodium, N-heterocyclic carbene ligands, Rhodium-NHC Complexes, Rhodium-Carbonyl Complexes, Influence of pressure, styrene, Influence of Temperature


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