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Letters in Organic Chemistry


ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Three Component Mannich Reaction and 1,5-Benzodiazepine Synthesis Catalyzed by a Tetranitrile-Silver Complex

Author(s): Gopalakrishnapanicker Rajesh Krishnan, Radhakrishnan Sreerekha and Krishnapillai Sreekumar

Volume 6, Issue 1, 2009

Page: [17 - 21] Pages: 5

DOI: 10.2174/157017809787003188

Price: $65


This manuscript describes the first example of silver ion complex of a dendritic tetranitrile ligand catalyzed one-pot three component Mannich reaction and 1,5-benzodiazepine synthesis. The catalyst can be separated from the products by a change in the solvent. The catalyst is reusable.

Keywords: Homogeneous catalysis, tetranitrile, silver complex, Mannich reaction, 2-aminoketones, 1,5 benzodiazepine

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