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Mini-Reviews in Organic Chemistry


ISSN (Print): 1570-193X
ISSN (Online): 1875-6298

Recent Applications of Phosphinite POCOP Pincer Complexes Towards Organic Transformations

Author(s): David Morales-Morales

Volume 5, Issue 2, 2008

Page: [141 - 152] Pages: 12

DOI: 10.2174/157019308784223578

Price: $65


Pincer complexes have represented a group of very important species in organometallic chemistry in the last decade. Among these, phosphinite POCOP pincer complexes have recently been used profusely in metal mediated organic transformations due to the easiness on their synthesis, high thermal stability and enhanced catalytic activity. This minireview presents the evolution and recent advances in the chemistry and applications of this important group of compounds in different cross coupling reactions and other transformations relevant in organic synthesis.

Keywords: Cross coupling reactions, POCOP pincer complexes, POCOP pincer ligands, Phosphinite complexes, Platinum group metal complexes, C-C Coupling Reactions, catalysis, PCP pincer compounds

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