Abstract
Hybrid bidentate phosphoramidite ligands are a recent family of promising phosphorus ligands. The different classes (phosphoramidite-phosphine, phosphoramidite-phosphite, phosphoramidite-phosphinite, phosphoramidite-thioethers, phosphoramidite-amine, phosphoramidite-NHC, phosphoramidite-oxazoline) are presented along with the strategies used to access to these compounds. The main part of the review summarizes the results of the evaluation of these ligands in reactions catalyzed by transition metals/bidentate phosphoramidite ligands, such as hydrogenation, hydroformylation, conjugate addition and Tsuji-Trost reaction.
Keywords: Hybrid bidentate ligands, phosphoramidites, asymmetric catalysis
Mini-Reviews in Organic Chemistry
Title: Hybrid Bidentate Phosphoramidite Ligands in Asymmetric Catalysis
Volume: 5 Issue: 2
Author(s): Fabien Boeda, Thomas Beneyton and Christophe Crevisy
Affiliation:
Keywords: Hybrid bidentate ligands, phosphoramidites, asymmetric catalysis
Abstract: Hybrid bidentate phosphoramidite ligands are a recent family of promising phosphorus ligands. The different classes (phosphoramidite-phosphine, phosphoramidite-phosphite, phosphoramidite-phosphinite, phosphoramidite-thioethers, phosphoramidite-amine, phosphoramidite-NHC, phosphoramidite-oxazoline) are presented along with the strategies used to access to these compounds. The main part of the review summarizes the results of the evaluation of these ligands in reactions catalyzed by transition metals/bidentate phosphoramidite ligands, such as hydrogenation, hydroformylation, conjugate addition and Tsuji-Trost reaction.
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Cite this article as:
Boeda Fabien, Beneyton Thomas and Crevisy Christophe, Hybrid Bidentate Phosphoramidite Ligands in Asymmetric Catalysis, Mini-Reviews in Organic Chemistry 2008; 5 (2) . https://dx.doi.org/10.2174/157019308784223613
DOI https://dx.doi.org/10.2174/157019308784223613 |
Print ISSN 1570-193X |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6298 |
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