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Mini-Reviews in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-193X
ISSN (Online): 1875-6298

P(t-Bu)3 : A Versatile and Efficient Ligand in Homogeneous Catalysis

Author(s): Jean Michel Brunel

Volume 1, Issue 3, 2004

Page: [249 - 277] Pages: 29

DOI: 10.2174/1570193043403163

Price: $65

Abstract

Changing substituents on phosphorus ligands can cause marked changes in the behaviour of the free ligands and of their transition metal complexes. In this review, we will describe the synthesis and the application of P(t-Bu)3, an efficient ligand in numerous homogeneous catalytic systems and rationalise its singular behaviour.

Keywords: tri-tert-butyl phosphine (p(t-bu)3), palladium, catalysis, amination, cross coupling


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