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Current Organic Synthesis

Editor-in-Chief

ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Benziodoxole-Based Hypervalent Iodine Reagents in Organic Synthesis

Author(s): Viktor V. Zhdankin

Volume 2, Issue 1, 2005

Page: [121 - 145] Pages: 25

DOI: 10.2174/1570179052996982

Price: $65

Abstract

Five-membered hypervalent iodine heterocycles derived from benziodoxole and benziodazole oxide have recently emerged as reagents of choice for various synthetically useful oxidative transformations. In particular, IBX (2-iodoxybenzoic acid) and DMP (Dess-Martin periodinane) are widely used for the selective oxidation of primary and secondary alcohols and for a variety of other important oxidations. IBX-amides and IBX-esters are a new class of pentavalent iodine reagents with a pseudo-benziodoxole structure and a reactivity pattern similar to IBX.

Keywords: hypervalent iodine, oxidation, benziodoxole, benziodazole, ibx, dmp


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