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Current Organic Synthesis

Editor-in-Chief

ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Palladium-Catalyzed Allylic Substitution Reaction in Polymer Synthesis

Author(s): N. Nomura, K. Tsurugi, N. Yoshida and M. Okada

Volume 2 , Issue 1 , 2005

Page: [21 - 38] Pages: 18

DOI: 10.2174/1570179052996973

Price: $65

Abstract

Polymer synthesis via the palladium-catalyzed allylic substitution reaction between allylic esters and malonic esters, namely the Tsuji-Trost reaction, is summarized in this review. Due to the versatility and potential of the Tsuji-Trost reaction, four polymerization patterns for various functionalized polymers have been reported.

Keywords: tsuji-trost reaction, allylpalladium, polymerization, allylation, palladium, polymer synthesis


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